According to the 1966 Motors Manual, the most likely causes of a 3 speed manual jumping out of gear include:
1. Linkage parts worn, bent, broken or out of adjustment.
2. Excessive end play caused by wear in shift forks, sliding gear fork grooves, thrust washers, mainshaft and countershaft bearings, or clutch pilot bushing.
3. Misalignment or excessive clearance between sliding gear and mainshaft.
4. Damaged synchronizer.
Per the 1960 Chevrolet Service Manual, the following issues should be considered specific to "slips out of high gear":
a. Transmission loose on clutch housing.
b. Dirt between transmission case and clutch housing.
c. Misalignment of transmission.
d. Clutch gear bearing retainer broken or loose.
e. Damaged mainshaft pilot bearing.
f. Shifter lock spring weak.
f. Clutch gear or second and third speed clutch improperly mated. (I'm not exactly sure what they mean by this).
If you're still using the factory column shift linkage, I'd start there looking for problems. These are famous for wearing so badly they won't control the transmission correctly. And it may not be worn, could be just loose parts. Should the problem be internal to the transmission, these old 3 speeds were about the easiest to rebuild. If you have decent mechanical skills you can replace the bearings, thrust washers and synchros yourself.
If it turns out there's damaged gears or parts inside, it may be easier and cheaper to replace the transmission with a guaranted rebuilt unit. Good luck, M.